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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">probener</journal-id><journal-title-group><journal-title xml:lang="ru">Известия высших учебных заведений. ПРОБЛЕМЫ ЭНЕРГЕТИКИ</journal-title><trans-title-group xml:lang="en"><trans-title>Power engineering: research, equipment, technology</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1998-9903</issn><issn pub-type="epub">2658-5456</issn><publisher><publisher-name>Kazan State Power Engineering  University</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.30724/1998-9903-2021-23-2-149-160</article-id><article-id custom-type="elpub" pub-id-type="custom">probener-1788</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>ЭНЕРГЕТИКА</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>POWER ENGINEERING</subject></subj-group></article-categories><title-group><article-title>Перспективные металлогидридные технологии хранения и очистки водорода</article-title><trans-title-group xml:lang="en"><trans-title>Prospective metal hydride hydrogen storage and purification technologies</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Блинов</surname><given-names>Д. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Blinov</surname><given-names>D. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Блинов Дмитрий Викторович, канд. техн. наук, ст. научн. сотр. лаборатории водородных энергетических технологий, Объединенный институт высоких температур РАН, доцент кафедры Химии и электрохимической энергетики, Национальный исследовательский университет «Московский энергетический институт»</p><p>Москва</p></bio><bio xml:lang="en"><p>Dmitry V. Blinov, Joint Institute for High Temperatures of the Russian Academy of Sciences, National Research University «Moscow Power Engineering Institute»</p><p>Moscow</p></bio><email xlink:type="simple">h2lab@mail.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Борзенко</surname><given-names>В. И.</given-names></name><name name-style="western" xml:lang="en"><surname>Borzenko</surname><given-names>V. I.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Борзенко Василий Игоревич, канд. техн. наук, заведующий лабораторией водородных энергетических технологий, Объединенный институт высоких температур РАН</p><p>Москва</p></bio><bio xml:lang="en"><p>Vasily I. Borzenko, Joint Institute for High Temperatures of the Russian Academy of Sciences</p><p>Moscow</p></bio><email xlink:type="simple">h2lab@mail.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Бездудный</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Bezdudny</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Бездудный Александр Владимирович, аспирант, Объединенный институт высоких температур РАН</p><p>Москва</p></bio><bio xml:lang="en"><p>Alexander V. Bezdudny, Joint Institute for High Temperatures of the Russian Academy of Sciences</p><p>Moscow</p></bio><email xlink:type="simple">h2lab@mail.ru</email><xref ref-type="aff" rid="aff-2"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кулешов</surname><given-names>Н. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Kuleshov</surname><given-names>N. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Кулешов Николай Васильевич, д-р техн. наук., профессор, заведующий кафедрой Химии и электрохимической энергетики, Национальный исследовательский университет «Московский энергетический институт»</p><p>Москва</p></bio><bio xml:lang="en"><p>Nikolay V. Kuleshov, National Research University «Moscow Power Engineering Institute»</p><p>Moscow</p></bio><email xlink:type="simple">h2lab@mail.ru</email><xref ref-type="aff" rid="aff-3"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>ОИВТ РАН; НИУ МЭИ</institution><country>Россия</country></aff><aff xml:lang="en"><institution>JIHT RAS; MPEI</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>ОИВТ РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>JIHT RAS</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-3"><aff xml:lang="ru"><institution>ОИВТ РАН</institution><country>Россия</country></aff><aff xml:lang="en"><institution>MPEI</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2021</year></pub-date><pub-date pub-type="epub"><day>21</day><month>05</month><year>2021</year></pub-date><volume>23</volume><issue>2</issue><fpage>149</fpage><lpage>160</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Блинов Д.В., Борзенко В.И., Бездудный А.В., Кулешов Н.В., 2021</copyright-statement><copyright-year>2021</copyright-year><copyright-holder xml:lang="ru">Блинов Д.В., Борзенко В.И., Бездудный А.В., Кулешов Н.В.</copyright-holder><copyright-holder xml:lang="en">Blinov D.V., Borzenko V.I., Bezdudny A.V., Kuleshov N.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.energyret.ru/jour/article/view/1788">https://www.energyret.ru/jour/article/view/1788</self-uri><abstract><p>ЦЕЛЬ. Разработать металлогидридные реакторы для хранения и очистки водорода различных типов. Интегрировать металлогидридные устройства хранения и очистки водорода с топливным элементом (ТЭ) и электролизером с твердополимерным электролитом. МЕТОДЫ. Для выплавки образцов интерметаллических соединений (ИМС) используется метод плавления в электродуговой печи с нерасходуемым вольфрамовым электродом на водоохлаждаемом медном кристаллизаторе в аргоновой атмосфере. Исследование интегральных характеристик металлогидридных устройств и исследование процессов при извлечении водорода из смеси газов проводится при помощи тепловых массовых измерителей расхода и термокондуктометрического газоанализатора. РЕЗУЛЬТАТЫ. Представлены результаты разработки и создания металлогидридных реакторов хранения и очистки водорода различных типов. Представлены результаты экспериментальных исследований системной интеграции металлогидридных реакторов, ТЭ и электролизера. ЗАКЛЮЧЕНИЕ. Аккумуляция энергии в водороде позволяет использовать минимально возможное давление газа в реакторе, тем самым получить предельную безопасность при эксплуатации устройства, а также избежать обязательной сертификации по безопасности и обучения личного персонала по работе с баллонами высокого давления. Применение металлогидридного способа проточной очистки показывает высокие показатели извлечения водорода для последующей аккумуляции и использования в ТЭ при больших объемных содержаниях водорода в смеси (≥10% об.), в то время как метод периодической эвакуации накопившихся примесей наиболее эффективен при низких содержаниях водорода в смеси (&lt;10% об.). Разработаны экспериментальные энергоустановки H&gt;2Bio и H2Smart электрической мощностью 200 Вт и 1 кВт, представлены результаты основных режимов работы энергоустановок.</p></abstract><trans-abstract xml:lang="en"><p>To develop metal hydride reactors for storage and purification hydrogen of various types. Integrate metal hydride hydrogen storage and purification devices with a fuel cell (FC) and an electrolyzer with a solid polymer electrolyte. METHODS. For the melting of samples of intermetallic compounds (IMC), the method of melting in an electric arc furnace with a non-consumable tungsten electrode on a water-cooled copper crystallizer in an argon atmosphere is used. The study of the integral characteristics of metal hydride devices and the study of the processes during the extraction of hydrogen from a mixture of gases is carried out using thermal mass flow meters and a thermoconductometric gas analyzer. RESULTS. The results of the development and creation of metal hydride reactors for the storage and purification of hydrogen of various types are presented. The results of experimental studies of the system integration of metal hydride reactors, fuel cells, and an electrolyzer are presented. CONCLUSION. The accumulation of energy in hydrogen makes it possible to use the lowest possible gas pressure in the reactor, thereby obtaining the maximum safety during operation of the device, as well as avoiding mandatory safety certification and training of personal personnel on working with high-pressure cylinders. The use of the metal hydride method of flow purification shows high rates of hydrogen extraction for subsequent accumulation and use in the fuel cell at high volume hydrogen contents in the mixture (≥10% vol.), while the method of periodic evacuation of accumulated impurities is most effective at low hydrogen contents in the mixture (&lt;10% vol.). Experimental power plants H&gt;2Bio and H2Smart with an electric power of 200 W and 1 kW are developed, the results of the main operating modes of power plants are presented.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>водородная энергетика</kwd><kwd>водород</kwd><kwd>металлогидриды</kwd><kwd>очистка водорода</kwd><kwd>интерметаллиды</kwd><kwd>водородная энергоустановка</kwd></kwd-group><kwd-group xml:lang="en"><kwd>hydrogen energy</kwd><kwd>hydrogen</kwd><kwd>metal hydrides</kwd><kwd>hydrogen purification</kwd><kwd>intermetalliс compounds</kwd><kwd>hydrogen power unit</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">International Energy Agency. The Future of Hydrogen, Seizing Today’s Opportunities // International Energy Agency: Paris, France, 2019.</mixed-citation><mixed-citation xml:lang="en">International Energy Agency. The Future of Hydrogen, Seizing Today’s Opportunitie International Energy Agency: Paris, France. 2019.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">IRENA, Hydrogen: A renewable energy perspective, International Renewable Energy Agency, Abu Dhabi, 2019.</mixed-citation><mixed-citation xml:lang="en">IRENA, Hydrogen: A renewable energy perspective, International Renewable Energy Agency, Abu Dhabi, 2019.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">REN21. Renewables 2020 Global Status Report. Paris: REN21 Secretariat 2020.</mixed-citation><mixed-citation xml:lang="en">REN21. Renewables 2020 Global Status Report. Paris: REN21 Secretariat 2020.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Kuleshov N.V.; Kuleshov V.N.; Dovbysh S.A., et al. Development and performances of a 0.5 kW high-pressure alkaline water electrolyser. International Journal of Hydrogen Energy, 2019,V.44. Issue 56. P. 29441-29449.</mixed-citation><mixed-citation xml:lang="en">Kuleshov NV, Kuleshov VN, Dovbysh SA, et al. Development and performances of a 0.5 kW high-pressure alkaline water electrolyser. International Journal of Hydrogen Energy. 2019;44(56):29441-29449.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">IRENA, Green Hydrogen Cost Reduction: Scaling up Electrolysers to Meet the 1.5⁰C Climate Goal, International Renewable Energy Agency, Abu Dhabi, 2020.</mixed-citation><mixed-citation xml:lang="en">IRENA, Green Hydrogen Cost Reduction: Scaling up Electrolysers to Meet the 1.5⁰C Climate Goal. International Renewable Energy Agency, Abu Dhabi, 2020.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Sołowski G., Konkol I., Cenian A. Methane and hydrogen production from cotton waste by dark fermentation under anaerobic and micro-aerobic conditions // Biomass and Bioenergy. 2020.V. 138. Pp. 105576.</mixed-citation><mixed-citation xml:lang="en">Sołowski G, Konkol I., Cenian A. Methane and hydrogen production from cotton waste by dark fermentation under anaerobic and micro-aerobic conditions. Biomass and Bioenergy. 2020;138:105576.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Khongkliang P., Jehlee A., Kongjan P., et al. High efficient biohydrogen production from palm oil mill effluent by two-stage dark fermentation and microbial electrolysis under thermophilic condition, International Journal of Hydrogen Energy. 2019. V.44. Issue 60. P. 31841-31852.</mixed-citation><mixed-citation xml:lang="en">Khongkliang P, Jehlee A, Kongjan P, et al. High efficient biohydrogen production from palm oil mill effluent by two-stage dark fermentation and microbial electrolysis under thermophilic condition, International Journal of Hydrogen Energy. 2019;44(60):31841-31852.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Zhiznin S.Z., Timokhov V.M., Gusev A.L. Economic aspects of nuclear and hydrogen energy in the world and Russia, International Journal of Hydrogen Energy. 2020. V. 45. Issue 56. P. 31353-31366.</mixed-citation><mixed-citation xml:lang="en">Zhiznin SZ, Timokhov VM, Gusev AL. Economic aspects of nuclear and hydrogen energy in the world and Russia. International Journal of Hydrogen Energy. 2020;45(56):31353-31366.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Fonseca J.D., Camargo M., Commenge J-M., et al. Trends in design of distributed energy systems using hydrogen as energy vector: A systematic literature review. International Journal of Hydrogen Energy, 2019. V.44. Issue 19. P. 9486-9504.</mixed-citation><mixed-citation xml:lang="en">Fonseca JD, Camargo M, Commenge J-M, et al. Trends in design of distributed energy systems using hydrogen as energy vector: A systematic literature review. International Journal of Hydrogen Energy. 2019;44(19):9486-9504.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Manickam K., Mistry P., Walker G., et al. Future perspectives of thermal energy storage with metal hydrides, International Journal of Hydrogen Energy2019. V.44. Issue 15. P. 7738-7745.</mixed-citation><mixed-citation xml:lang="en">Manickam K, Mistry P, Walker G, et al. Future perspectives of thermal energy storage with metal hydrides. International Journal of Hydrogen Energy. 2019;44(15):7738-7745.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Nyamsi S.N., Lototskyy M., Tolj I. Selection of metal hydrides-based thermal energy storage: Energy storage efficiency and density targets, International Journal of Hydrogen Energy. 2018. V.43. Issue 50. P. 22568-22583.</mixed-citation><mixed-citation xml:lang="en">Nyamsi SN, Lototskyy M, Tolj I. Selection of metal hydrides-based thermal energy storage: Energy storage efficiency and density targets, International Journal of Hydrogen Energy. 2018;43(50):22568-22583.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Sun D.-W., Deng S.-J. A theoretical model predicting the effective thermal conductivity in powdered metal hydride beds // International Journal of Hydrogen Energy. 1990. V. 15. № 5. pp 331-336.</mixed-citation><mixed-citation xml:lang="en">Sun D.-W, Deng S.-J. A theoretical model predicting the effective thermal conductivity in powdered metal hydride beds. International Journal of Hydrogen Energy.1990;15(5):331-336.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Артемов В.И., Лазарев Д.О., Яньков Г.Г., и др. Влияние неабсорбируемых газовых примесей на процессы тепломассообмена в металлогидридных устройствах для аккумулирования и очистки водорода // Теплофизика высоких температур. 2004. T. 42. № 6. C. 972.</mixed-citation><mixed-citation xml:lang="en">Artemov VI, Lazarev DO, YAn'kov GG, et al. Vliyanie neabsorbiruemyh gazovyh primesej na processy teplomassoobmena v metallogidridnyh ustrojstvah dlya akkumulirovaniya i ochistki vodoroda Teplofizika vysokih temperatur.2004;42(6):972.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Sandrock G.D., Goodell P. D. Cyclic life of metal hydrides with impure hydrogen: Overview and engineering considerations // Journal of the Less Common Metals. 1984. V. 104. № 1. P. 159-173.</mixed-citation><mixed-citation xml:lang="en">Sandrock GD, Goodell PD. Cyclic life of metal hydrides with impure hydrogen: Overview and engineering considerations. Journal of the Less Common Metals. 1984;104(1):159-173.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Тарасов Б.П., Шилкин С.П. Взаимодействие интерметаллических соединений LaNi5 и CeCo3 с водородом в присутствии Ar, CH4 и CO2 // Журнал неорганической химии, 1994. C. 18-22.</mixed-citation><mixed-citation xml:lang="en">Tarasov BP, SHilkin SP. Vzaimodejstvie intermetallicheskih soedinenij LaNi5 i CeCo3 s vodorodom v prisutstvii Ar, CH4 i CO2. ZHurnal neorganicheskoj himii. 1994. pp. 18-22.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Glagoleva A.A., Blinov D.V., Borzenko V.I. Novel kW scale hydrogen energy storage system utilizing fuel cell exhaust air for hydrogen desorption process from metal hydride reactor. Energy. 2019. V.183. P. 1244-1252.</mixed-citation><mixed-citation xml:lang="en">Glagoleva AA, Blinov DV, Borzenko VI. Novel kW scale hydrogen energy storage system utilizing fuel cell exhaust air for hydrogen desorption process from metal hydride reactor. Energy. 2019;183:1244-1252.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Han G., Kwon YK., Kim J.B., et al. Development of a high-energy-density portable/mobile hydrogen energy storage system incorporating an electrolyzer, a metal hydride and a fuel cell, Applied Energy. 2020. V. 259. pp.114175.</mixed-citation><mixed-citation xml:lang="en">Han G, Kwon YK, Kim JB., et al. Development of a high-energy-density portable/mobile hydrogen energy storage system incorporating an electrolyzer, a metal hydride and a fuel cell. Applied Energy. 2020;2591:141-175.</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Казаков А.Н., Дуников Д.О., Борзенко В.И. Разработка методики изготовления и исследования образцов интерметаллических соединений для систем хранения и очистки биоводорода // Вестник Московского энергетического института. 2014. №3. С. 17-21.</mixed-citation><mixed-citation xml:lang="en">Kazakov AN, Dunikov DO, Borzenko VI. Razrabotka metodiki izgotovleniya i issledovaniya obrazcov intermetallicheskih soedinenij dlya sistem hraneniya i ochistki biovodoroda. Vestnik Moskovskogo energeticheskogo instituta. 2014;3:17-21.</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Borzenko V.I, Romanov I.A.,. Dunikov D.O, et al. Hydrogen sorption properties of metal hydride beds: Effect of internal stresses caused by reactor geometry, International Journal of Hydrogen Energy. 2019. V44. Issue 12. P. 6086-6092.</mixed-citation><mixed-citation xml:lang="en">Borzenko VI, Romanov IA. Dunikov DO, et al. Hydrogen sorption properties of metal hydride beds: Effect of internal stresses caused by reactor geometry. International Journal of Hydrogen Energy. 2019;44(12):6086-6092.</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Artemov V.I., Minko K.B., Yan'kov G.G. Numerical study of heat and mass transfer processes in a metal hydride reactor for hydrogen purification. International Journal of Hydrogen Energy. 2016. V.41. Issue 23. P. 9762-9768.</mixed-citation><mixed-citation xml:lang="en">Artemov VI, Minko KB, Yan'kov GG. Numerical study of heat and mass transfer processes in a metal hydride reactor for hydrogen purification. International Journal of Hydrogen Energy. 2016;41:9762-9768.</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Nashchekin M.D., Minko K.B., Artemov V.I. Numerical analysis of constructive and regime parameter effects on the efficiency of metal hydride systems for hydrogen purification. Case Studies in Thermal Engineering. 2019.V. 14. P. 100485.</mixed-citation><mixed-citation xml:lang="en">Nashchekin MD, Minko KB, Artemov VI. Numerical analysis of constructive and regime parameter effects on the efficiency of metal hydride systems for hydrogen purification. Case Studies in Thermal Engineering. 2019;14:100485.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
