Estimation of energy efficiency of kraft pulp production with the exergy increment method
https://doi.org/10.30724/1998-9903-2020-22-2-3-11
Abstract
This article contains results of exergic analysis of kraft pulping flow chart. The results of exergic balances of main kraft pulping processes such as alkali recovery at recovery boilers, black liquor evaporation, chips cooking, lime decarbonation are considered in details in the article. The analysis of the process flow chart makes it possible to determine the bottlenecks in the use of heat energy and to substantiate principal lines for increasing energy efficiency of the processes under study. A main share of the exergy expended in the existing pulping process is due to alkali recovery in the recovery boiler and comprises 70% of the total exergy available in the system. A procedure of hydrothermal production of chemicals in the process of kraft pulping is studied. A schematic diagram and analysis of heat technique of the kraft pulping process which in fact consists of organic component removal from black liquor through its autoclave carbonation with flue gases releasing from lime kiln at the temperature 80-90 oC are given in the article. The removal of organic components under these conditions can reach 70 %. In the studied version the exergic efficiency ηe = 80 % is considerably higher than that of the flow chart existing for chemicals recovery which is equal to ηe = 48 %. This is the evidence of high energy efficiency of the method developed.
About the Author
Р. V. LukaninRussian Federation
Pavel V. Lukanin
Saint Petersburg
References
1. Kazakov VG, Lukanin PV, Smirnova OS. Uproshchennyi metod opredeleniya eksergeticheskogo KPD slozhnoi teplovoi skhemy tekhnologicheskogo protsessa. Promyshlennaya energetika. 2010;1:38-41.
2. Kalinin N.V., Martynov A.V., Kalinina E.I. Ob eksergii i KPD (K Jubeleju uchitelja) Holodil’naja tekhnika. 2019;10:42-45.
3. Yushkova EA, Lebedev VA. Opredelenie eksergii v teplotekhnicheskikh sistemakh. Nauchnaya konferentsiya «Nauka. Issledovaniya.Praktika», 24 Feb 2020; Saint-Peterburg, Russia. Saint-Peterburg: GNII «Natsrazvitie», 2020. pp. 184-186.
4. Lukanin PV, Kazakov VG, Fyedorova OV. Energoekologicheskie aspecty v protsesse pererabotki chyernogo shcheloka sul’fatnoi tsellyulozy. XX Mendeleevskiy s’ezd po obshchei i prikladnoi khimii; 26-30 Sen 2016; Ekaterinburg, Russia. Ekaterinburg: Uralskoye otdelenie Rossiiskoi Akademii Nauk, 2016. P. 512.
5. Timpe W., Evers W. A new process for the recovery of heat and chemicals from black liquor from cellulose sulfate production using hydropyrolysis. Pulp and Piper. 1972;11: 56-7.
6. Ma Keo P. Rapid pyrolysis of black sulfate liquor. Papery I Puu. 1995;1-2: 39-44.
7. Vagin GYa. K voprosu o povyshenii energeticheskoi effektivnosti promyshlennykh predpriyatii // Promyshlennaya energetika. 2013;5: 2-6.
8. Kazakov VG, Lukanin PV, Smirnova OS. Gidrokhimicheskii sposob regeneratsii natrievykh shchelochei. Patent RUS № 2415984. 10.04.2011. Byul. №10.
9. Alén R, Sjöström E, Vaskirari P. Carbon dioxide precipitation of lignin from alkaline pulping liquors. Cellulose Chemistry and Technology. 1985;19 (5): 537-541.
10. Lukanin PV, Kazakov VG, Fyedorova OV,et al. Modernizatsiya tekhnologicheskogo processa pererabotki chyernykh shchelokov sul’fatnoi tsellyulozy. Prikladnaya khimiya. 2016; 89(5):654-659.
11. Lukanin PV, Kazakov VG, Smirnova OS. Tekhnologiya teploty v gidrokhimicheskom sposobe regeneratsii khimikatov proizvodstva sul’fatnoi tsellyulozy. Promyshlennaya energetika. 2012; 11: 44-8.
12. Nimish Dubey, Morrish Kumar. CFD Analysis of Fluid Flowing Through a Heat Exchanger Tube Having a Twisted Tape with a Centrally Placed Semi-Circular Groove. International Journal of Science and Research. 2017;6 (6):2200-7.
13. Hansen E, Panwar R, Vlosky R. The Global Forest Sector: Changes. Practices and Prospects. Taylor & Francis Group (NY);2017.
14. Sivashanmugam P, Suresh S. Experimental studies on heat transfer and friction factor characteristics of turbulent flow through a circular tube fitted with helical screw-tape inserts. Chemical Engineering and Processing. 2007;46:1292-8.
15. Shyy Woei Chang, Wei Ling Cai, Ruo Sin Syu. Heat transfer and pressure drop measurements for tubes fitted with twin and four twisted fins on rod. Experimental Thermal and Fluid Science. 2016; 74: 220-234.
16. Zhang Z, Way JD, Wolden CA, et al. Вarium-promoted ruthenium catalysts on yittriastabilized zirconia supports for ammonia synthesis. ACS Sustainable Chemistry and Engineering. 2019; 7(21):18038-18047.
Review
For citations:
Lukanin Р.V. Estimation of energy efficiency of kraft pulp production with the exergy increment method. Power engineering: research, equipment, technology. 2020;22(2):3-11. (In Russ.) https://doi.org/10.30724/1998-9903-2020-22-2-3-11