Mass emissions of polycyclic aromatic hydrocarbons during fuel combustion in thermal power plant boilers

   RELEVANCE of this study lies in the establishment of technological indicators of emissions of benz(a)pyrene into the atmosphere to assess the degree of negative impact of energy enterprises on the environment and the development on this basis of primary (air protection) measures, inventory of emissions ofpollutants, collection and preparation of initial environmental information for the effective implementation of the principles of technological regulation of emissions in the domestic thermal power industry. THE

   PURPOSE. The technological features of the formation of polycyclic aromatic hydrocarbons, in particular benz(a)pyrene, in the furnaces of power boilers burning organic fuel are considered.

   The regime factors significantly influencing the intensity of the formation of benz(a)pyrene as the most carcinogenic and mutagenic impurity in
flue gases have been determined. As part of the implementation of the principles of technological rationing of polluting marker substances, energy enterprises should determine the mass emission of highly toxic combustion products to improve the environmental performance of combustion processes and establish technological emission indicators.

   METHODS. Determination of mass emissions of polycyclic aromatic hydrocarbons was carried out using methods of mathematical statistics, processing of environmental information, system analysis of data and processing of the results obtained.

   RESULTS. Analytical expressions have been developed to determine the content of benz(a)pyrene in the combustion products of coal and anthracite. The values of mass emissions of benz(a)pyrene for inventory and justification of technological rationing of carcinogenic and mutagenic substances at energy enterprises have been determined.

   CONCLUSION. The results obtained are recommended to be used for a preliminary assessment of the content of benz(a)pyrene in the flue gases of boilers at power plants at the stage of collecting and preparing information for the introduction of technological rationing of highly toxic substances and the assessment of technological emission indicators.

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