Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms
https://doi.org/10.30724/1998-9903-2019-21-3-4-3-6
Abstract
With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.
It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.
The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.
By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen.
About the Authors
L. R. Gaynullina
Kazan State Power Engineering University
Russian Federation
Russian Federation
Leysan R. Gaynullina.
V. P. Tutubalina
Kazan State Power Engineering University
Russian Federation
Russian Federation
Valeria P. Tutubalina.
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Review
For citations:
Gaynullina L.R., Tutubalina V.P. Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms. Power engineering: research, equipment, technology. 2019;21(3-4):3-6. https://doi.org/10.30724/1998-9903-2019-21-3-4-3-6
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